a. Positive radicals:
b. Basic radicals:
c. Composite radicals:
d. Metals with variable valency:
e. Bivalent acidic radicals:
f. Trivalent basic radicals:
(Mercury, potassium, nitrogen, copper, sulphur, carbon, chlorine, oxygen)
Mercury: Symbol: | Radicals: Mercurous or Mercuric
Potassium: Symbol: | Radical: Potassium ion
Nitrogen: Symbol: | Radical: Nitride ion
Copper: Symbol: | Radicals: Cuprous or Cupric
Sulphur: Symbol: | Radical: Sulphide ion
Carbon: Symbol: | Radical: Carbide ion (Carbon also forms complex radicals like carbonate ).
Chlorine: Symbol: | Radical: Chloride ion
Oxygen: Symbol: | Radical: Oxide ion
(Sodium sulphate, potassium nitrate, ferric phosphate, calcium oxide, aluminium hydroxide)
A. Sodium sulphate:
Write the symbols of the basic radical () and acidic radical ().
Write their valencies below them: has valency , and has valency .
Cross-multiply the valencies: .
Formula:
B. Potassium nitrate:
Write symbols: and .
Write valencies: is , is .
Cross-multiply: .
Formula:
C. Ferric phosphate:
Write symbols: (ferric means valency 3) and (valency 3).
Simplify the ratio ( becomes ) and cross-multiply: .
Formula:
D. Calcium oxide:
Write symbols: and .
Write valencies: is , is .
Simplify ratio ( becomes ) and cross-multiply: .
Formula:
E. Aluminium hydroxide:
Write symbols: and .
Write valencies: is , is .
Cross-multiply: .
Formula:
a. Explain the monovalency of the element sodium.
b. M is a bivalent metal. Write down the steps to find the chemical formulae of its compounds formed with the radicals : sulphate and phosphate
Answer
With Sulphate (): Metal M has valency , and sulphate has valency . Simplifying the ratio gives . Cross-multiplying gives .
With Phosphate (): Metal M has valency , and phosphate has valency . Cross-multiplying gives .
c. Explain the need for a reference atom for atomic mass. Give some information about two reference atoms.
Answer Atoms are far too tiny to be weighed directly on a scale, so scientists needed a relative scale using a "reference atom" to compare how heavy different elements are.
First reference atom (Hydrogen): Initially chosen because it is the lightest element, with an assigned mass of .
Second reference atom (Oxygen): Later used because oxygen readily reacts with many different elements.
Modern standard: Today, carbon-12 is universally used as the standard reference.
d. What is meant by Unified Atomic Mass?
e. Explain with examples what is meant by a 'mole' of a substance.
Answer A mole is a standard counting unit in chemistry used to measure the amount of a substance. One mole of any substance always contains a fixed number of particles ( particles, known as Avogadro's number).
a.
Name: Sodium sulphate
Calculation:
b.
Name: Potassium carbonate
Calculation:
c.
Name: Carbon dioxide
Calculation:
d.
Name: Magnesium chloride
Calculation:
e.
Name: Sodium hydroxide
Calculation:
f.
Name: Aluminium phosphate
Calculation:
g.
Name: Sodium bicarbonate (Sodium hydrogen carbonate)
Calculation:
Answer
Law Proved: This proves the Law of Constant Proportions.
Simple Explanation & Calculation:
In Sample m ( total): Mass of calcium = , Mass of oxygen = . The ratio of calcium to oxygen is .
In Sample n ( total): Mass of calcium = , Mass of oxygen = . The ratio of calcium to oxygen is .
Even though the samples differ in total weight and were made using different reactions, the elements are always combined in the exact same fixed proportion by mass, which is what the Law of Constant Proportions states.
(32g oxygen, 90g water, 8.8g carbon dioxide, 7.1g chlorine)
Beginner-Friendly Logic: To find molecules, find the moles first () and multiply by Avogadro's number ().
Calculations:
a. 32g oxygen ():
Molecular mass = . Moles = .
Molecules = .
b. 90g water ():
Molecular mass = . Moles = .
Molecules = .
c. 8.8g carbon dioxide ():
Molecular mass = . Moles = .
Molecules = .
d. 7.1g chlorine ():
Molecular mass = . Moles = .
Molecules = .
(Sodium chloride, magnesium oxide, calcium carbonate)
Beginner-Friendly Logic: To find grams, multiply moles by molecular mass ().
Calculations:
a. Sodium chloride ():
Molecular mass = .
Grams = .
b. Magnesium oxide ():
Molecular mass = .
Grams = .
c. Calcium carbonate ():
Molecular mass = .
Grams = .